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Growth and characterization of Fe3O4 films
Authors:Jian Ding  Makoto Arita  Kazuki Nakamura  Qixin Guo
Affiliation:a State Key Laboratory of Metal Matrix Composites, Shanghai Jiaotong University, Shanghai 200240, China
b Department of Materials Science and Engineering, Kyushu University, Fukuoka 819-0395, Japan
c Synchrotron Light Application Center, Department of Electrical and Electronic Engineering, Saga University, Saga 840-8502, Japan
Abstract:Iron oxide films were grown on sapphire substrates by pulsed laser deposition at substrate temperatures between 100 and 700 °C. X-ray diffraction, Raman spectroscopy, and vibrational sample magnetometer analysis revealed that structural and magnetic properties of the iron oxide films strongly depend on the substrate temperature during growth. Single phase Fe3O4 film was successfully grown on sapphire substrate at a substrate temperature of 500 °C. The saturation magnetic moment of the single phase Fe3O4 film is 499 emu/cm3, which is in good agreement with the value reported for bulk magnetite, suggesting the Fe3O4 film is of high crystal quality without antiphase boundaries.
Keywords:Electronic materials   Laser deposition   Raman spectroscopy   Magnetic properties
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