| 无硫黑火药的热分解动力学研究 |
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| 引用本文： | 俞进阳,陈利平,姜夕博,彭金华.无硫黑火药的热分解动力学研究[J].含能材料,2011,19(6):646-649. |
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| 作者姓名： | 俞进阳 陈利平 姜夕博 彭金华 |
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| 作者单位： | 南京理工大学化工学院安全工程系,江苏南京,210094 |
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| 基金项目： | 国家科技支撑计划课题基金资助(2008BAK40B01) |
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| 摘 要： | 用差示扫描量热仪,在四种升温速率下,测定了KNO3/C=65/30,KNO3/C=75/15两种组分配比的无硫型黑火药的DSC曲线,并与普通黑火药的热分解数据与热行为进行了对比.在实验结果对比分析的基础上,运用Kissinger、Ozawa和(S)atava-(S)esták方程求解了黑火药发生热分解时的活化能和指前因...
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| 关 键 词： | 物理化学 黑火药 热分解 差示扫描量热法(DSC) 活化能 |
| 收稿时间： | 2010/10/26 0:00:00 |
| 修稿时间： | 7/1/2011 2:48:14 PM |
Thermal Kinetics of Sulphur-free Black Powder |
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| YU Jin-yang,CHEN Li-ping,JIANG Xi-bo and PENG Jin-hua.Thermal Kinetics of Sulphur-free Black Powder[J].Chinese Journal of Energetic Materials,2011,19(6):646-649. |
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| Authors: | YU Jin-yang CHEN Li-ping JIANG Xi-bo and PENG Jin-hua |
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| Affiliation: | Department of Safety Engineering, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China;Department of Safety Engineering, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China;Department of Safety Engineering, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China;Department of Safety Engineering, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China |
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| Abstract: | |
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| Keywords: | physical chemistry black powder thermal decomposition DSC active energy |
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