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Ferroelectric phase transition in Ba5RTi3Nb7O30 [R=Nd, Eu, Gd] ceramics
Authors:R N P Choudhary  S R Shannigrahi  A K Singh
Affiliation:(1) Department of Physics, Indian Institute of Technology, 721 302 Kharagpur, India
Abstract:Polycrystalline samples of Ba5RTi3Nb7O30 R=Nd, Eu, Gd], were prepared using high-temperature solid-state reaction technique. Preliminary X-ray structural analysis of the compounds shows the formation of single phase compounds (orthorhombic crystal system) at room temperature. Detailed studies of dielectric properties (ɛ, tanδ,σ) as a function of frequency (400 Hz to 10 kHz) and temperature (30° to 380°C) show that these compounds exhibit diffuse ferroelectric phase transition.
Keywords:Polycrystalline  ferroelectric  tungsten-bronze structure  dielectric constant  electrical conduction
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