Rapid pyrolysis and CO2 gasification of anthracite at high temperature |
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Authors: | Qiongliang Zha Jing Zhao Changan Wang Defu Che |
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Affiliation: | State Key Laboratory of Multiphase Flow in Power Engineering, School of Energy and Power Engineering, Xi''an Jiaotong University, Xi''an 710049, China |
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Abstract: | Anthracite could be burnt efficiently at high temperature utilizing oxy-coal technology. To clarify the effects of temperature and atmosphere on char porosity characteristics, char morphology, fuel-N conversion, and reducing products release, rapid pyrolysis and CO2 gasification of anthracite was carried out in a high temperature entrained-flow reactor to simulate the condition in a pulverized coal furnace. Developed pore structure was formed in the gasification chars, which could be contributed to char![/>CO<sub>2</sub> reaction at high temperatures. More mesopores were formed in internal carbon skeleton and retained against collapse and coalescent for gasification chars than pyrolysis chars. Compared with pyrolysis char, smoother and denser surface was observed in gasification char with the irregular bulges disappeared due to the destruction of external carbon skeleton. Char-N could be oxidized to NO in CO<sub>2</sub> atmosphere and then reduced to N<sub>2</sub> by (<img style=](https://sdfestaticassets-eu-west-1.sciencedirectassets.com/shared-assets/16/entities/sbnd) | |
Keywords: | Anthracite High temperature Char porosity Fuel-N conversion |
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