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基体表面状态对聚乙烯涂层结合强度的影响
引用本文:李国丽,王雪明. 基体表面状态对聚乙烯涂层结合强度的影响[J]. 涂料工业, 2007, 37(2): 58-60,63
作者姓名:李国丽  王雪明
作者单位:1. 山东大学胶体与界面化学教育部重点实验室,济南,250100;山东轻工业学院轻化与环境工程学院,济南,250100
2. 北京航空航天大学材料科学与工程学院,北京,100083;山东大学材料液态结构与遗传性教育部重点实验室,济南,250061
基金项目:山东省优秀中青年科学家科研奖励基金
摘    要:利用砂纸打磨、酸冼、磷化、喷砂、KH-560硅烷处理等不同表面预处理工艺对Q235钢基体进行预处理。并在不同表面状态的钢基体上制备聚乙烯涂层,研究了不同预处理工艺对聚乙烯涂层结合强度的影响。结果表明:传统表面处理工艺提高涂层结合强度有限,而KH-560硅烷处理可以显著提高涂层结合强度,较用传统的砂纸打磨(60^#)、酸冼、磷化、喷砂处理工艺分别提高了40.3%、46%、17.6%和13.2%,而涂层的破断形式也有别于传统的处理方法,为内聚断裂;“喷砂+KH-560”预处理法可以获得最大的涂层结合强度。

关 键 词:硅烷偶联剂  聚乙烯  涂层  结合强度  表面预处理
文章编号:0253-4312(2007)02-0058-04
修稿时间:2006-12-11

Effects of Substrate Surface Condition on the Adhesive Strength of Polyethylene Coatings
Li Guoli,Wang Xueming. Effects of Substrate Surface Condition on the Adhesive Strength of Polyethylene Coatings[J]. Paint & Coatings Industry, 2007, 37(2): 58-60,63
Authors:Li Guoli  Wang Xueming
Affiliation:1. Key Lab for Colloid and Interface Chemistry of Education Ministry, Shandong University, Jinan 250100, China; 2. School of Light Chemical and Environmental Engineering, Shandong Institute of Light Industry, Jinan 250100, China; 3. School of Material Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100083, China; d. Key Lab for Liquid Structure and Heredity of Ministry of Education, Shandong University, Jinan 250061, Chian
Abstract:Polyethylene coatings was applied on Q235 steel substrate surface with different surface conditions pretreated by sandpaper grinding, acid etching, phosphating, blasting and KH -560 respectively, and the effect of various pretreatments on the adhesive strength of polyethylene coatings was investigated in this paper. The results showed that the traditional pretreatments had a limited improvement for the adhesive strength, but KH -560 pretreatment can increased adhesive strength significantly which was higher than those with sandpaper grinding, acid etching, phosphating, and blasting by 40. 3%, 46%, 17.6% and 13.2% respectively, and that the highest adhesive strength can be obtained when the substrates were pretreated by the blend pretreatment of blasting and KH -560.
Keywords:silane coupling agents    polyethylene    coatings    adhesive strength    surface pretreatment
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