| 1,4-双(氯甲基)-2-甲氧基-5-辛氧基苯及聚合物的合成 |
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| 引用本文： | 李银奎,王建营,龙永福,黄钐.1,4-双(氯甲基)-2-甲氧基-5-辛氧基苯及聚合物的合成[J].高分子材料科学与工程,1999,15(6):56-58,61. |
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| 作者姓名： | 李银奎 王建营 龙永福 黄钐 |
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| 作者单位： | 国防科技大学材料工程与应用化学系,长沙,410073 |
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| 摘 要： | 由对甲氧基苯酚（ＭＯＰｈ）合成出一种可溶性电致发光共轭聚合物聚（２－甲氧基－５－辛氧基）亚苯基亚乙烯（ＰＭＯＯＯＰＶ）大致过程为：由ＭＯＰｈ与１－溴辛烷合成１－甲氧基－４－辛氧基苯（ＭＯＯＯＢ）继而合成了１，４－双（氯甲基）－２－甲氧基－５－辛氧基苯（ＢＣＭＭＯＯＯＢ）碱性聚合得可溶性ＰＭＯＯＯＰＶ。并做了ＢＣＭＭＯＯＯＢ与其它单体的共聚，对中间体及聚合物用＾１ＨＮＭＲ进行了表征。
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| 关 键 词： | 电致发光聚合物 聚(2-甲氧基-5-辛氧基)亚苯基亚乙烯 聚合 |
SYNTHESIS OF 1,4-BIS(CHLOROMETHYL)-2-METHOXY-5-OCTYLOXYBNEZENE AND ITS POLYMERS |
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| Li Yinkui,Wang Jianying,Long Yongfu,Huang Shan.SYNTHESIS OF 1,4-BIS(CHLOROMETHYL)-2-METHOXY-5-OCTYLOXYBNEZENE AND ITS POLYMERS[J].Polymer Materials Science & Engineering,1999,15(6):56-58,61. |
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| Authors: | Li Yinkui Wang Jianying Long Yongfu Huang Shan |
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| Affiliation: | Li Yinkui, Wang Jianying, Long
Yongfu, Huang Shan
(The Department of Material Engineering and Applied Chemistry,
The National University of Defence Technology, Changsha) |
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| Abstract: | A kind of electroluminescent material, poly(2 methoxy 5 octyloxy) phenylene vinylene(PMOOOPV) is synthesized by using 4 methoxyphenol(MOPh) as raw material. PMOOOPV is soluble in CHCl 3, but infusible. The soluble copolymer of 1,4 bis(chloromethyl) 2 methoxy 5 octyloxybenzene and 1,4 bis(chloromethyl) 2 methoxy 5 ethoxybenzene is synthesized also. The structure of monomers, polymer and copolymer were determined by 1HNMR. |
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| Keywords: | poly(2 methoxy 5 octyloxy) phenylene vinylene 1 4 bis(chloromethyl) 2 methoxy 5 octyloxybenzene 1 4 bis(chloromethyl) 2 methoxy 5 ethoxybenzene electroluminescent devices light emitting diode polymerization |
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