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2,6-萘二甲酸二甲酯在有机溶剂中溶解度的测定与关联
引用本文:夏清,马沛生. 2,6-萘二甲酸二甲酯在有机溶剂中溶解度的测定与关联[J]. 中国化学工程学报, 2007, 15(2): 215-220. DOI: 10.1016/S1004-9541(07)60061-5
作者姓名:夏清  马沛生
作者单位:School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
摘    要:Solubility of dimethyl-2,6-naphthalene dicarboxylate in acetic acid, N,N-dimethylfonnamide, N,N-dimethyl acetamide, dimethyl sulphoxide, and N-methyl-2-ketopyrrolidine were determined using a dynamic method. The measured systems were correlated by UNIFAC group contribution method. A new main group (aromatic ester, ACCOO) was defined to express the activity coefficients of the aromatic ester. New interaction parameters of the ACCOO group were expressed as the first-order function of temperature and were determined from the experimental data. The calculated results for the new interaction parameters were satisfactory. The measured systems were also correlated with the Wilson and 2-h models, and the results were compared with those of the UNIFAC model.

关 键 词:2,6-萘二甲酸二甲酯  有机溶剂  溶解度  测量  校正
收稿时间:2006-02-21
修稿时间:2006-02-212006-06-12

Measurement and correlation for solubility of dimethyl-2,6-naphthalene dicarboxylate in  organic solvents
XIAQing,MAPeisheng. Measurement and correlation for solubility of dimethyl-2,6-naphthalene dicarboxylate in  organic solvents[J]. Chinese Journal of Chemical Engineering, 2007, 15(2): 215-220. DOI: 10.1016/S1004-9541(07)60061-5
Authors:XIAQing  MAPeisheng
Affiliation:School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
Abstract:Solubility of dimethyl-2,6-naphthalene dicarboxylate in acetic acid,N,N-dimethyl acetamide,dimethyl sulphoxide,and N-methyl-2-ketopyrrolidine were determined using a dynamic method.The measured systems were correlated by UNIFAC group contribution method.A new main group (atomatic ester, ACCOO) was defined to express the activity coefficients of the aromatic ester.New interaction parameters of the ACCOO group were expressed as the first-order function of temperature and were determined from the experimental data.The calculated results for the new interaction parameters were satisfactory.The measured systems were also correlated with the Wilson and λ-h models,and the results were compared with those of the UNIFAC model.
Keywords:solid-liquid equilibrium  solubility  dimethyl-2  6-naphthalene dicarboxylate  UNIFAC group contribution method  activity coefficient
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