| 水介质中原子转移自由基聚合的研究进展 |
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| 引用本文： | 朱严瑾,彭慧,徐祖顺,易昌凤.水介质中原子转移自由基聚合的研究进展[J].高分子材料科学与工程,2006,22(2):11-15. |
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| 作者姓名： | 朱严瑾 彭慧 徐祖顺 易昌凤 |
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| 作者单位： | 湖北大学化学与材料科学学院,湖北,武汉,430062 |
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| 基金项目： | 湖北省科技厅青年杰出人才基金 |
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| 摘 要： | 作为一种新兴的可控/活性聚合方法,原子转移自由基聚合(ATRP)兼具了自由基聚合与可控/活性聚合的优点。水作为一种环境友好性的溶剂,使其作为ATRP的反应介质有着强烈的吸引力。文中从均相水溶液体系以及悬浮、乳液、微乳液等非均相水溶液体系,分别介绍了近年来水介质中ATRP的研究进展,并对其发展方向进行了展望。
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| 关 键 词： | 水介质 原子转移自由基聚合 可控/活性自由基聚合 |
| 文章编号： | 1000-7555（2006）02-0011-05 |
| 收稿时间： | 2005-01-22 |
| 修稿时间： | 2005-04-07 |
DEVELOPMENT OF ATOM TRANSFER RADICAL POLYMERIZATION IN AQUEOUS MEDIA |
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| ZHU Yan-jin,PENG Hui,XU Zu-shun,YI Chang-feng.DEVELOPMENT OF ATOM TRANSFER RADICAL POLYMERIZATION IN AQUEOUS MEDIA[J].Polymer Materials Science & Engineering,2006,22(2):11-15. |
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| Authors: | ZHU Yan-jin PENG Hui XU Zu-shun YI Chang-feng |
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| Affiliation: | College of Chemistry and Material Science, Hubei University, Wuhan 430062, China |
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| Abstract: | Atom transfer radical polymerization,a newborn and intersectional subject in controlled/living polymerization,has the virtues of both the traditional radical process and controlled/living polymerization.Water is an environmentally friendly solvent,which makes it attractive medium for atom transfer radical polymerizations.In this paper,recent researches and developments on atom transfer radical polymerization in aqueous media have been introduced from the aspect of homogeneous aqueous system and various heterogeneous system,such as suspension,emulsion,miniemulsion. |
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| Keywords: | aqueous media atom transfer radical polymerization controlled/living polymerization |
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