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CdSnO3纳米材料的室温固相合成及其气敏特性研究
引用本文:徐甲强,沈嘉年,王焕新,荆熠. CdSnO3纳米材料的室温固相合成及其气敏特性研究[J]. 传感技术学报, 2004, 17(2): 265-268
作者姓名:徐甲强  沈嘉年  王焕新  荆熠
作者单位:郑州轻工业学院材料化工学院,郑州,450002;上海大学材料研究所,上海,200072;上海大学材料研究所,上海,200072;郑州轻工业学院材料化工学院,郑州,450002
基金项目:河南省高校杰出科研人才创新工程项目,河南省杰出青年科学基金
摘    要:以无机盐为原料,在遵守热力学限制的前提下,采用室温固相化学反应法合成了复合氧化物CdSnO3,X-射线粉末衍射(XRD)、透射电镜(TEM)等表征结果表明,固相反应完全,产物为β-CdSnO3,其粒径为30 nm左右,与传统方法相比,该法降低了CdSnO3的物相形成温度.气敏性能测试结果表明,以该法合成的CdSnO3为基体的气敏元件,对体积分数0.005%酒精的灵敏度高达63.6倍,抗干扰能力强,响应-恢复快,为应用前景良好的酒敏材料.

关 键 词:偏锡酸镉  纳米材料  气体传感器  固相化学反应
文章编号:1004-1699(2004)02-0265-04
修稿时间:2003-10-02

Gas Sensitivity of CdSnO3 Nanosized Powder Synthesized by Solid2StateReaction at Room Temp
XU Jiaqiang,SHEN Jianian,WANG Huanxin,JING Yi. Gas Sensitivity of CdSnO3 Nanosized Powder Synthesized by Solid2StateReaction at Room Temp[J]. Journal of Transduction Technology, 2004, 17(2): 265-268
Authors:XU Jiaqiang  SHEN Jianian  WANG Huanxin  JING Yi
Affiliation:XU Jia-qiang 1,2,SHEN Jia-nian2,WANG Huan-xin1,JING Yi11. College of Material and Chemical Engineering,Zhengzhou Institute of Light Industry,Zhengzhou 450002,China, 2. Materials Institute of Shanghai University,Shanghai 200072,China
Abstract:Nanometer CdSnO 3 was synthesized by solid-state reaction with inorganic reagents at room temperature. The results from XRD and TEM indicate that the solid-state reaction is complete and feasible; the mean sizes of the CdSnO 3powders are 30 nm. The gas-sensing measurements results reveal that the sensors based on CdSnO 3 show a high sensitivity and selectivity to ethanol gas. And its sensitivity to 0 005% alcohol gas is up to 63 6 times. Thus, this complex oxide is a promising ethanol-sensing material.
Keywords:CdSnO 3  nanometer material  gas sensor  solid state reaction
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