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Study of phenol removal using fluidized-bed Fenton process
Authors:Li Zhou  Jianxun Hu  Hong Zhong  Xueping Li
Affiliation:1. School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China;2. Department of Mechanical Engineering, Hunan Institute of Technology, Hengyang 421002, China;3. Department of Mechanical Engineering, Milwaukee School of Engineering, Milwaukee, WI 53201, United States
Abstract:In this paper, the removal of phenol from simulated wastewater was studied using gas–liquid fluidized bed with the Fenton reagent. The factors that affect the removal rate of phenol were investigated, including the initial concentrations of hydrogen peroxide [H2O2] and [Fe2+], the molar ratio of [Fe2+]/[H2O2], pH value, temperatures, reaction time, and the ventilation volume. It was found that the optimal operating conditions existed as: [H2O2] = 12 mmol/L, [H2O2]/[Fe2+] = 4:1, pH = 4, T = 60 °C, reaction time of 30 min, and a ventilation volume of 0.12 m3/h. Under these conditions, the phenol removal rate of about 96% was obtained.
Keywords:Phenol wastewater   Fenton reagent   Phenol removal rate   Fluidized-bed
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