Methodologies for chemical utilization of CO2 to valuable compounds through molecular activation by efficient catalysts |
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| Authors: | Liangnian He Ya Du Chengxia Miao Jinquan Wang Xiaoyong Dou and Ying Wu |
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| Affiliation: | (1) State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071, China |
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| Abstract: | The reactions of CO2 with oxirane to produce cyclic carbonate, and with aziridine to afford oxazolidine have been of interest as a useful method
for its fixation by a chemical process. Highly efficient processes employing recyclable CO2-phlilic homogeneous catalyst were devised for environmentally benign synthesis of cyclic carbonates and oxazolidinones under
supercritical CO2 without any organic solvent. These processes represent pathways for greener chemical fixations of CO2 to afford industrial useful materials such as organic carbonates and oxazolidinones with great potential applications. |
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| Keywords: | carbon dioxide chemical utilization molecular catalyst carbonate oxazolidinone |
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