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Thermodynamic modeling and assessment of a combined coal gasification and alkaline water electrolysis system for hydrogen production
Authors:    r Sacit Herdem,Siamak Farhad,Ibrahim Dincer,Feridun Hamdullahpur
Affiliation:1. Department of Mechanical & Mechatronics Engineering, University of Waterloo, 200 University Avenue West, Waterloo, ON N2L 3G1, Canada;2. Department of Mechanical Engineering, University of Akron, Akron, OH 44325-3903, United States;3. Faculty of Engineering and Applied Science, University of Ontario Institute of Technology (UOIT), 2000 Simcoe Street North, Oshawa, ON L1H 7K4, Canada
Abstract:The performance of a clean energy system that combines the coal gasification and alkaline water electrolyzer concepts to produce hydrogen is evaluated through thermodynamic modeling and simulations. A parametric study is conducted to determine the effect of water ratio in coal slurry, gasifier temperature, effectiveness of carbon dioxide removal, and hydrogen recovery efficiency of the pressure swing adsorption unit on the system hydrogen production. The exergy efficiency and exergy destruction in each system component are also evaluated. The results reveal that the overall energy and exergy efficiencies of this system are ∼58% and ∼55%, respectively. The weight ratio of the hydrogen yielded to the coal fed to this system is ∼0.126. Although this system produces hydrogen from coal, the greenhouse gases emitted from this system are fairly low.
Keywords:Hydrogen production   Coal gasification   Alkaline electrolyzer   Thermodynamic modeling   Exergy analysis
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