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Experimental study on high temperature catalytic conversion of tars and organic sulfur compounds
Authors:Urs Rhyner  Philip EdingerTilman J. Schildhauer  Serge M.A. Biollaz
Affiliation:Paul Scherrer Institut (PSI), 5232 Villigen PSI, Switzerland
Abstract:A 400 cpsi noble metal catalyst was used to test the conversion of tars and sulfur containing hydrocarbons in the presence of steam, hydrogen sulfide and ethene. In order to reproduce producer gas from biomass gasification, higher molecular hydrocarbons (toluene, naphthalene, phenanthrene, pyrene) and sulfur containing hydrocarbons (thiophene, benzothiophene, dibenzothiophene) were added to a syngas. The syngas consisted of H2, CH4, H2O, CO, CO2 and N2. The catalyst was operated at temperatures between 620 °C and 750 °C and at gas hourly space velocity (GHSV) of 9000 h−1 and 18,000 h−1.
Keywords:Noble metal catalyst   Desulfurization   Hot gas cleaning   Tar removal   Biomass
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