Pt catalyst supported on titanium suboxide for formic acid electrooxidation reaction |
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| Authors: | Huiru Zhao Yi Wang Qinghu Tang Li Wang Hui Zhang Can Quan Tao Qi |
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| Affiliation: | 1. National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, PR China;2. School of Chemistry and Chemical Engineering, Key Laboratory of Green Chemical Media and Reaction, Ministry of Education, Henan Normal University, Xinxiang 453007, PR China;3. College of Petrochemical Technology, Lanzhou University of Technology, Lanzhou 730050, PR China;4. Division of Chemistry, National Institute of Metrology, Beijing 100013, PR China |
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| Abstract: | Pt catalysts supported on titanium suboxide (Ti4O7), commercial TiO2 and carbon black were prepared by a borohydride reduction method, respectively, and used as electrocatalysts for direct formic acid fuel cells (DFAFCs). Transmission electron microscopy (TEM) images show that Pt nanoparticles have a poorer dispersion on Ti4O7 compared to that on TiO2 and carbon black due to the hydrophobicity and high density of Ti4O7. Nevertheless, according to cyclic voltammetry (CV) and chronoamperometry (CA) results, it is found that the Pt/Ti4O7 catalyst possesses better catalytic activity and stability. Besides the high electrical conductivity, it is suggested from X-ray photoelectron spectroscopy (XPS) analyses that the higher content of metallic Pt caused by the Ti4O7 support material also contributes to the better catalytic performance of Pt/Ti4O7. |
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| Keywords: | Pt/Ti4O7 catalyst Formic acid electrooxidation Support material Catalytic activity Fuel cell |
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