Asymmetric induction in forming poly(olefin sulphone)s |
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Authors: | Allan H Fawcett R Karl Malcolm |
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Affiliation: | Laboratoire des Matériaux Macromoléculaires, URA CNRS 507, Institut National des Sciences Appliquées de Lyon, Bǎt. 403, 20, avenue A. Einstein, 69621 Villeurbanne Cedex, France |
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Abstract: | Poly(1-olefin sulphone)s have been prepared from olefins with a chiral centre at the carbon atom adjacent to the double bond. In 13C and 1H NMR studies on the polymers obtained by free radical copolymerisation it has been found that the chirality of a main chain methine carbon that forms part of the backbone depends upon the chirality of the carbon initially present within the same hydrocarbon residue. The introduction of bulky groups into the chiral group of the monomeric olefin increased the ratio of diastereoisomers formed within the residue. In the most favoured case 69% of the backbone chiral centres were fixed with reference to the side chain structures. By employing a simple theory based upon an enumeration of steric interactions and upon the γ-gauche effect on carbon chemical shifts, it was deduced that the main chain chiral centre preferred to adopt the opposite stereochemistry to that of the side chain when that carries an ethyl group, a methyl group and a hydrogen atom. A bias was also found at the backbone when the monomer chiral centre contained polar acid or ester groups. |
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Keywords: | poly(olefin sulphone)s microstructure 13C NMR spectroscopy asymmetric induction free radical copolymerisation |
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