Thin-film rechargeable lithium batteries |
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Affiliation: | 1. Center for Energy Storage Research, Korea Institute of Science and Technology (KIST), Seoul, 02792, Republic of Korea;2. Division of Energy & Environment Technology, KIST School, Korea University of Science and Technology, Seoul, 02792, Republic of Korea;3. Department of Materials Science and Engineering, Korea University, Seoul, 02841, Republic of Korea;4. Department of Energy and Materials Engineering, Dongguk University, Seoul, 04620, Republic of Korea;5. Department of Energy Engineering, Hanyang University, Seoul, 04763, Republic of Korea;1. Eskişehir Osmangazi University, Physics Department, 26480, Eskişehir, Turkey;2. Bilecik Şeyh Edebali University, Chemistry Department, Bilecik Turkey;1. School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu, 611731, China;2. Guizhou Province Key Laboratory of Metallurgical Engineering and Process Energy Savingy, College of Materials and Metallurg, Guizhou University, Guiyang, 550025, China |
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Abstract: | Thin-film rechargeable batteries with a lithium metal anode, an amorphous inorganic electrolyte, and cathodes of amorphous V2O5 and crystalline and amorphous LixMn2O4 have been fabricated and characterized. The performance of the thin-film cells was evaluated at different current densities and, in the case of Li V5, at several temperatures. Electrical measurements show that the current density of the thin-film cells is limited by the lithium-ion mobility in the cathodes. The resistance of Li LixMn2O4 cells with crystalline cathodes is about two orders of magnitude lower than that of Li V5 cells with amorphous cathodes. |
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