Synthesis and structure of a new cobalt-containing aluminophosphate |
| |
| Affiliation: | 1. Department of Industrial Engineering, Business School, University of Shanghai for Science and Technology, 516 Jungong Road, Shanghai 200093, PR China;2. Department of Operations Management, Antai College of Economics & Management, Shanghai Jiao Tong University, 1954 Huashan Road, Shanghai 200030, PR China;3. Department of Mechanical Engineering, The University of Texas at San Antonio, San Antonio, TX 78249-0670, USA;1. School of Management and Economics, Beijing Institute of Technology, Beijing, China;2. Institute Charles Delaunay, Université de Technologie de Troyes, Troyes, France;3. Department of Mechanical and Industrial Engineering, Norwegian University of Science and Technology, Trondheim, Norway;4. Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing, China |
| |
| Abstract: | We report on the synthesis and single-crystal structure of a novel cobalt-substituted aluminophosphate. Crystal data: monoclinic, space group (no. 14), a = 8.593(1), b = 15.540(1), c = 7.736(1)Å, β = 110.65(1)°, V = 966.7(4)Å3, Z = 4, R = 0.037, and Rw = 0.029 for 2280 contributing reflections and 182 variables. Refined framework-atom bond distances and angles exhibited regular tetrahedral coordination of Al and P [dave(AlO) = 1.74(1)Å, dave(PO) = 1.54(2)Å] and distorted Co-centered octahedra. The Co substituted every second aluminum in the ordered AlP distribution and was coordinated to five framework oxygen atoms and to one nitrogen atom from a template ethylenediamine molecule located in an eight-member ring opening. Structure collapsed in the absence of template. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
