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Stress and recovery maxima in LDPE melt elongation
Authors:Thomas Raible  Anton Demarmels  Joachim Meissner
Affiliation:(1) Department of Industrial and Engineering Chemistry, Swiss Federal Institute of Technology (ETHZ), 8092 Zürich, Switzerland
Abstract:Summary By means of a new tensile rheometer for polymer melts, stress-strain curves sgr(epsi) and the elastic recovery epsiR(epsi) of a low density polyethylene melt were measured up to total strains epsi=7, i.e. stretch lambda=1097, at 150°C and two strain rates, epsi=0.03 and 0.1 s–1. Tensile tests up to very high strains e give relevant results only if the test performance is characterized by quality parameters which are defined and given in this paper. The test results show a maximum in a as well as in epsiR at about epsi=5.5. Hence, in the range of epsi investigated, a rheologically steady-state of flow does not exist.
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