| 甲基丙烯酸改性聚醋酸乙烯乳液胶粘剂研究 |
| |
| 引用本文： | 刘海英,顾继友,谭海彦,李建新.甲基丙烯酸改性聚醋酸乙烯乳液胶粘剂研究[J].粘接,2010,31(3):33-36. |
| |
| 作者姓名： | 刘海英 顾继友 谭海彦 李建新 |
| |
| 作者单位： | 1. 东北林业大学材料科学与工程学院,黑龙江,哈尔滨,150040
2. 江苏银龙电力电缆有限公司,江苏,徐州,221700 |
| |
| 基金项目： | 哈尔滨市攻关项目"E0级排放(不含甲醛和苯)胶粘剂关键技术，东北林业大学青年科研基金 |
| |
| 摘 要： | 采用半连续种子乳液聚合法，以甲基丙烯酸（MAA）为功能性单体，考查MAA的加入量、加入方式和中和度对乳液耐水性能的影响，合成了醋酸乙烯／叔碳酸乙烯酯／甲基丙烯酸（VAc／Veova10／MAA）三元共聚乳液。改性共聚乳液干强度为951MPa，湿强度为377MPa，吸水性为47．0％。电导滴定法分析MAA共聚后，部分竣基基团分布于乳胶粒子表面。提高乳液的耐水性能；扫描电镜（SEM）观察乳胶颗粒分散均匀。合成的共聚乳液可用作木材胶粘剂。
|
| 关 键 词： | 聚醋酸乙烯 乳液 耐水性 甲基丙烯酸 |
Effect of MAA on water resistance of VAc/ Veova10 latex wood adhesives |
| |
| LIU Hai-ying,GU JI-you,TAN Hai-yan,LI Jian-xun.Effect of MAA on water resistance of VAc/ Veova10 latex wood adhesives[J].Adhesion in China,2010,31(3):33-36. |
| |
| Authors: | LIU Hai-ying GU JI-you TAN Hai-yan LI Jian-xun |
| |
| Affiliation: | LIU Hai-ying1,GU Ji-you1,TAN Hai-yan1,LI Jian-xin2 (1.College of Material Science and Engineering,Northeast Forestry University,Harbin,Heilongjiang 150040,China,2. Jiang Su Yin Long Power Cable Co.,Ltd.,Xuzhou,Jiangsu 221700,China) |
| |
| Abstract: | Water-resistant copolymer latexes of vinyl acetate(VAc)/vinyl ester of versatic acid(Veova)/ methacrylic acid (MAA)were prepared by the semi-continuous seeding emulsion polymerization. The water resistance of these latexes was greatly dependent on the MAA content, the introduction method of MAA and the neutralization degree of MAA. The results showed that water-resistant VAc/ Veova /MAA latex had 9.51 MPa of dry compression shear strength , 3.77 MPa of wet compression shear strength and 47.0% of water absor... |
| |
| Keywords: | plolyvinyl acetate latex or emulsion water resistance methacrylic acid |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
