| 天然橡胶接枝甲基丙烯酸羟乙酯的合成与表征 |
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| 引用本文： | 陈丽,曾幸荣,李红强,赖学军,王永洪. 天然橡胶接枝甲基丙烯酸羟乙酯的合成与表征[J]. 化学与粘合, 2012, 0(3): 15-17,53 |
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| 作者姓名： | 陈丽 曾幸荣 李红强 赖学军 王永洪 |
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| 作者单位： | 华南理工大学材料科学与工程学院,广东广州510640 |
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| 摘 要： | 以甲基丙烯酸羟乙酯(HEMA)为接枝单体,过氧化二苯甲酰(BPO)为引发剂,合成了天然橡胶(NR)接枝聚甲基丙烯酸羟乙酯(NR-g-HEMA)。研究了BPO和HEMA用量、反应温度、反应时间以及NR塑炼时间对单体转化率、接枝率和接枝效率的影响,并采用红外光谱对接枝产物进行了表征。结果表明:当BPO用量为3%,HEMA用量为30%,反应温度为80℃,反应时间和NR塑炼时间分别为4h和30min时,NR-g-HEMA的接枝率达16%。
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| 关 键 词： | 天然橡胶 甲基丙烯酸羟乙酯 接枝反应 |
Synthesis and Characterization of Natural Rubber Grafted with 2-Hydroxyethyl Methacrylate |
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| CHEN Li,ZENG Xing-rong,LI Hong-qiang,LAI Xue-jun and WANG Yong-hong. Synthesis and Characterization of Natural Rubber Grafted with 2-Hydroxyethyl Methacrylate[J]. Chemistry and Adhesion, 2012, 0(3): 15-17,53 |
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| Authors: | CHEN Li ZENG Xing-rong LI Hong-qiang LAI Xue-jun WANG Yong-hong |
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| Affiliation: | (College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China) |
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| Abstract: | Natural rubber grafted with poly （2-hydroxyethyl methacrylate）（NR-g-HEMA） was synthesized with using HEMA as grafting monomer and BPO as initiator. The effects of the amount of BPO and HEMA, reaction temperature and time, and the mastification time of NR on the conversion rate, grafting ratio and grafting efficiency of monomer were investigated. The NR-g-HEMA was characterized by FT-IR. The results showed when the amount of BPO was 3%, the amount of HEMA was 30%, reaction temperature was 80℃, reaction time and NR mastification time was dh and 30min respectively, the grafting ratio of NR-g-HEMA reached 16%（wt）. |
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| Keywords: | Natural rubber 2-hydroxyethyl methacrylate grafting |
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