| 低游离醛高羟甲基含量酚醛树脂的合成 |
| |
| 引用本文： | 伏传龙,鲁钢,魏无际,敖文亮,朱文元.低游离醛高羟甲基含量酚醛树脂的合成[J].热固性树脂,2004,19(5):17-19,23. |
| |
| 作者姓名： | 伏传龙 鲁钢 魏无际 敖文亮 朱文元 |
| |
| 作者单位： | 1. 南京工业大学材料科学与工程学院,江苏,南京,210009
2. 常州天马集团,江苏,常州,213000 |
| |
| 摘 要： | 通过实验,以CaO作催化剂合成了低游离醛高羟甲基含量酚醛树脂。采用正交试验方法研究了催化剂用量、反应温度、反应时间对酚醛树脂的游离醛含量、羟甲基含量2个指标的影响。当n(苯酚)∶n(甲醛)=1∶1 2～1 3时,最优工艺条件为:n(催化剂)∶n(苯酚)物质的量比0 02、反应温度70℃、反应时间3h。
|
| 关 键 词： | 酚醛树脂 正交试验 低游离醛 高羟甲基 |
| 文章编号： | 1002-7432(2004)05-0017-04 |
SYNTHESIS OF PF RESINS CONTAINING HIGH METHYLOL GROUP CONTENT AND LOW FREE FORMALDEHYDE CONTENT |
| |
| FU Chuan-long,LU Gang.SYNTHESIS OF PF RESINS CONTAINING HIGH METHYLOL GROUP CONTENT AND LOW FREE FORMALDEHYDE CONTENT[J].Thermosetting Resin,2004,19(5):17-19,23. |
| |
| Authors: | FU Chuan-long LU Gang |
| |
| Affiliation: | FU Chuan-long~1,LU Gang~ |
| |
| Abstract: | In this paper,PF resins with low free formaldehyde and higher methylol content was synthesized with CaO as catalyst.The influence of different quantity of catalyst,reaction time and reaction temperature on the indexes of content of free formaldehyde and content of methylol group was investigated by means of orthogonal experiments.The major,secondary factors were given and the optimum technological condition about the course of reaction was (quantity of catalyst) 0.02;reaction temperature,70 ℃;reaction time,3 h. |
| |
| Keywords: | PF resins orthogonal experiment low-free formaldehyde high methylol group |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
