| 5-(4-(3-二甲氧基甲基硅烷基丙氧基)苯基)-1H-四氮唑的合成 |
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| 引用本文： | 牛春朋,李惠萍,王东杰,郝玲芳. 5-(4-(3-二甲氧基甲基硅烷基丙氧基)苯基)-1H-四氮唑的合成[J]. 精细石油化工, 2011, 28(3): 9-12 |
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| 作者姓名： | 牛春朋 李惠萍 王东杰 郝玲芳 |
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| 作者单位： | 郑州大学化工与能源学院,河南郑州,450001 |
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| 摘 要： | 以对羟基苯甲腈和叠氮钠为主要原料,采用点击化学法环加成合成-种质子导体5-(4-(3-二甲氧基甲基硅烷基丙氧基)苯基)-1H-四氮唑.通过单因素法考察了反应物配比、时间、温度对中间物5-(4-羟基苯基)-四氮唑收率的影响.最佳工艺条件为:n(对羟基苯甲腈)∶n(叠氮钠)=1∶1.4,130℃,24 h,50℃下酸化1....
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| 关 键 词： | 5-(4-羟基苯基)-四氮唑 5-(4-(3-二甲氧基甲基硅烷基丙氧基)苯基)-1H-四氮唑 点击化学 对羟基苯甲腈 叠氮钠 |
SYNTHESIS OF 5-(4-(3-( DIMETHOXY (METHYL) SILYL)PROPOXY) PHENYL)-1H-TETRAZOLE |
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| Niu Chunpeng,Li Huiping,Wang Dongjie,Hao Lingfang. SYNTHESIS OF 5-(4-(3-( DIMETHOXY (METHYL) SILYL)PROPOXY) PHENYL)-1H-TETRAZOLE[J]. Speciality Petrochemicals, 2011, 28(3): 9-12 |
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| Authors: | Niu Chunpeng Li Huiping Wang Dongjie Hao Lingfang |
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| Affiliation: | Niu Chunpeng,Li Huiping,Wang Dongjie and Hao Lingfang (School of Chemical Engineering and Energy,Zhengzhou University,Zhengzhou 450001,He'nan,China) |
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| Abstract: | Because of conjugate structure,azole nitrogen molecules can form a series of compounds, which have electrochemical stability.5-(4-(3-(Dimethoxy(methyl) silyl) propoxy) phenyl)-1H-tetrazole (B) was synthesized by click chemistry through cycloaddition and condensation reactions,that could be used for the preparation of new proton exchange membrane.In the synthesis of 5-(4- hydroxyphenol)-1H- tetrazole(A) experiments,the influences of same factors on product yield were investigated,such as the ratio of reactan... |
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| Keywords: | 5-(4-hydroxyphenol)-1H-tetrazole 5-(4-(3-(dimethoxy(methyl)silyl)propoxy)phenyl)-1H-tetrazole click chemistry 4-hydroxybenzonitrile sodium azide |
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