| 希夫碱类金属配合物催化剂催化氧化烯烃研究进展 |
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| 引用本文： | 冯辉霞,李汉峰,王利杰. 希夫碱类金属配合物催化剂催化氧化烯烃研究进展[J]. 应用化工, 2011, 40(2): 315-318,334 |
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| 作者姓名： | 冯辉霞 李汉峰 王利杰 |
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| 作者单位： | 兰州理工大学,石油化工学院,甘肃,兰州,730050 |
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| 基金项目： | 国家自然科学基金,甘肃省自然科学基金资助项目,国家科技部科技人员服务企业行动项目,兰州理工大学博士基金 |
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| 摘 要： | 分析了希夫碱金属配合物的结构特点及其催化氧化烯烃的研究现状,阐述了用于均相催化氧化的希夫碱、固载型希夫碱金属配合物催化剂的分类及其在氧化烯烃领域的应用研究。通过分析希夫碱类小分子金属配合物催化氧化烯烃的缺陷,得出非均相的负载型希夫碱类金属配合物催化剂是目前主要发展方向的结论。
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| 关 键 词： | 希夫碱 金属配合物 烯烃 负载 催化氧化 |
Progress in research of Schiff base metal complexes catalytic using for olefins catalytic oxidation |
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| FENG Hui-xia,LI Han-feng,WANG Li-jie. Progress in research of Schiff base metal complexes catalytic using for olefins catalytic oxidation[J]. Applied chemical industry, 2011, 40(2): 315-318,334 |
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| Authors: | FENG Hui-xia LI Han-feng WANG Li-jie |
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| Affiliation: | (College of Petrochemical Technology,Lanzhou University of Technology,Lanzhou 730050,China) |
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| Abstract: | The structure of metal complexes characteristic of Schiff base was analyzed and catalytic oxidation olefins was studied on current situation systematically.And it expressed the classification application of Schiff base which used in type of homogeneous catalysis oxidization and metal complexes of solid catalyst.By analyzing the defects of small molecules metal complexes catalysis-oxidization olefins,the conclusion indicated that the heterogeneous load type of metal complexes of Schiff base in category catalyst is the main development direction in present. |
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| Keywords: | Schiff base metal complexes olefin supported catalytic oxidation |
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