| 新型Salen-卟啉金属配合物催化剂的研究 |
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| 引用本文： | 苏建玲,赵文军,张富昌,高利柱,高林. 新型Salen-卟啉金属配合物催化剂的研究[J]. 应用化工, 2007, 36(4): 390-393 |
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| 作者姓名： | 苏建玲 赵文军 张富昌 高利柱 高林 |
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| 作者单位： | 1. 中国科学院,新疆理化技术研究所,新疆,乌鲁木齐,830011;中国科学院,研究生院,北京,100039
2. 中国科学院,新疆理化技术研究所,新疆,乌鲁木齐,830011 |
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| 摘 要： | 以5-对氨基苯基-10,15,20-三苯基卟啉和水杨醛为原料,合成水杨醛缩氨基四苯基卟啉,分别加入Ni(NO3).26H2O和Mn(OAc)2.4H2O,经络合反应,合成了两个同时具有卟啉结构和Salen结构的配合物3a和3b,产率分别为75%和80%,各化合物均通过UV-Vis,IR,1HNMR,元素分析进行表征。将配合物3a和3b应用于环己烷的催化氧化,环己烷的转化率分别达到了8.25%和12.45%。
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| 关 键 词： | 卟啉 席夫碱 配合物 二聚体 |
| 文章编号： | 1671-3206(2007)04-0390-04 |
| 修稿时间： | 2007-02-08 |
Study of complexes of Salen-porphyrin |
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| SU Jian-ling,ZHAO Wen-jun,ZHANG Fu-chang,GAO Li-zhu,GAO Lin. Study of complexes of Salen-porphyrin[J]. Applied chemical industry, 2007, 36(4): 390-393 |
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| Authors: | SU Jian-ling ZHAO Wen-jun ZHANG Fu-chang GAO Li-zhu GAO Lin |
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| Affiliation: | 1. Xinjiang Technical Institute of Physics and Chemistry, the Chinese Academy of Sciences, Urumqi 830011, China;2. Graduate University of Chinese Academy of Sciences, Beijing 100039 ,China |
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| Abstract: | 5-(4-salicylidene amino phenyl)-10,15,20-triphenyl-porphyrin were synthesized from 5-(4-amidophenyl)-10,15,20-triphenyl-porphyrin and salicylaldehyde.The Salen-porphyrin complexes 3a and 3b were obtained after complexing with Ni(NO3)2·6H2O and Mn(OAc)2·4H2O with the yields of 75% and 80% respectively.The structure of these compounds were characterized by the UV-Vis,IR,1H NMR and elemental analysis.The complexes 3a and 3b were applied in reaction of catalytic oxidation of cyclohexane,the conversion of cyclohexane achieved 8.25% and 12.45% respectively. |
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| Keywords: | porphyrin schiff base complex dimer |
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