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烟气氧硫比对软锰矿浆烟气脱硫体系浸锰过程及脱硫产物的影响
引用本文:孙维义,苏仕军,丁桑岚,蒋文举,李玉洁. 烟气氧硫比对软锰矿浆烟气脱硫体系浸锰过程及脱硫产物的影响[J]. 高校化学工程学报, 2011, 25(1): 143-148
作者姓名:孙维义  苏仕军  丁桑岚  蒋文举  李玉洁
作者单位:四川大学,国家烟气脱硫工程技术研究中心,四川,成都,610065
基金项目:国家863计划项目(2008AA06Z316)
摘    要:基于烟气中氧气与二氧化硫浓度之间的关系对软锰矿浆烟气脱硫反应的影响机理分析,提出用氧硫比(氧气与二氧化硫的摩尔比)作为关联烟气含氧量与二氧化硫浓度的参数,考察了烟气氧硫比对软锰矿浆烟气脱硫体系锰浸出率及脱硫产物的影响,据此探讨了提高锰浸出率与硫酸锰产量的方法.结果表明,氧硫比是体系pH值变化的指针因子,并通过改变体系的...

关 键 词:氧硫比  催化氧化  pH  锰浸出率  硫酸锰

Effect of O2 / SO2 Ratio in the Flue Gas on Manganese Extract Process and Byproduct in the Process of Flue Gas Desulfurization with Pyrolusite Pulp
SUN Wei-yi,SU Shi-jun,DING Sang-lan,JIANG Wen-ju,LI Yu-jie. Effect of O2 / SO2 Ratio in the Flue Gas on Manganese Extract Process and Byproduct in the Process of Flue Gas Desulfurization with Pyrolusite Pulp[J]. Journal of Chemical Engineering of Chinese Universities, 2011, 25(1): 143-148
Authors:SUN Wei-yi  SU Shi-jun  DING Sang-lan  JIANG Wen-ju  LI Yu-jie
Affiliation:SUN Wei-yi,SU Shi-jun,DING Sang-lan,JIANG Wen-ju,LI Yu-jie(National Engineering Research Center of Flue Gas Desulfurization,Sichuan University,Chengdu 610065,China)
Abstract:Based on analyzing the mechanism of the effect of the relationship between the concentration ratio of O2 and SO2 in the flue gas on the desulphurization reaction,the O2/SO2(molar ratio) was put forward as a correlated parameter for the concentrations of O2 and SO2 in the flue gas.The effect of O2/SO2 on the Mn2+ extraction ratio and byproduct formation were investigated,and the measures for increasing Mn2+ extraction ratio and output of MnSO4 were presented.The results show that the O2/SO2 is the decisive f...
Keywords:ratio of O2 to SO2  catalysis oxidation  pH  Mn2 extraction ratio  manganese sulfate  
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