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化学助剂在过氧化氢漂白中的应用
引用本文:邵震宇,谢益民. 化学助剂在过氧化氢漂白中的应用[J]. 造纸化学品, 2008, 20(2): 25-28
作者姓名:邵震宇  谢益民
作者单位:山东轻工业学院,制浆造纸工程省级重点学科,山东,济南,250353
摘    要:过氧化氢已成为无元素氯(ECF)和全无氯(TCF)漂白的重要漂白剂,但在漂白过程中,浆中过渡金属离子的存在会引起过氧化氢发生无效分解产生游离基,并导致碳水化合物的降解,降低漂白效果。在漂白过程中适当加入些助剂,除去浆中的过渡金属离子,加强过氧化氢的漂白能力,来提高漂白效果,改善漂白工艺。

关 键 词:过氧化氢漂白  螯合剂  稳定剂  缓冲剂  活化剂
文章编号:1007-2225(2008)02-0025-04
修稿时间:2007-09-05

Application of Chemical Additives in Hydrogen Peroxide Bleaching
SHAO Zhen-yu,XIE Yi-min. Application of Chemical Additives in Hydrogen Peroxide Bleaching[J]. Paper Chemicals, 2008, 20(2): 25-28
Authors:SHAO Zhen-yu  XIE Yi-min
Affiliation:(Key Lab of Paper science and Technology of Ministry of Education, Shandong Institute of Light Industry, Jinan 250353, China)
Abstract:Hydrogen peroxide has been an important oxidant in ECF and TCF bleaching sequences. However, the inefficient decompositions of hydrogen peroxide promoted by transition metal ions in pulp will produce hydroxyl radicals, which degrade carbohydrates and reduce the bleaching efficiency. To enhance the bleaching efficiency of H2O2 and improve the bleaching process, some bleaching additives were used to remove the transition metals.
Keywords:hydrogen peroxide bleaching  chelating agent  stabilizer  buffering agent  activator
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