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The ablation behavior of ZrB2/Cu composite irradiated by high-intensity continuous laser
Affiliation:1. School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China;2. National Key Laboratory of Science and Technology on Materials under Shock and Impact, Beijing 100081, China;1. School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China;2. National Key Laboratory of Science and Technology on Materials under Shock and Impact, China;1. Shanghai Collaborative Innovation Center for High Performance Fiber Composites, Center for Civil Aviation Composites, Donghua University, Shanghai, 201620, PR China;2. Composite Center, AVIC Manufacturing Technology Institute, National Key Laboratory of Advanced Composites, Beijing, 101300, PR China;3. Luoyang Optoelectro Technology Development Center, Luoyang, Henan, 471009, PR China;1. School of Materials Science and Engineering, Beijing Institute of Technology, Beijing, 100081, China;2. Beijing Institute of Technology Chongqing Innovation Center, Chongqing, 401120, China;3. Beijing Key Laboratory of Space Thermal Control Technology, Beijing Institute of Spacecraft System Engineering, Beijing, 100094, China
Abstract:Ultra high temperature ceramics (UHTCs) based composite ZrB2/20 vol.% Cu was prepared by spark plasma sintering (SPS) at 1650 C° for 3 min. The ablation behavior of composite irradiated for 2–20 s by 20 MW/m2 high-intensity continuous laser was investigated. The phase and microstructure evolution of ZrB2/20 vol.% Cu during ablation was demonstrated by XRD and SEM, respectively. The results reveal that no macroscopic damage but only one ablated layer with 40 μm in thickness is observed even after being ablated for 20 s. It implies that ZrB2/20 vol.% Cu composite exhibits good ablation resistance against high-intensity continuous laser. The continuous Cu in composite evaporates preferentially, which impacts on the following ablation behavior. The generated ZrO2 at the spot center shows different forms such as closely packed nano-ZrO2, micron ZrO2 or melting ZrO2 for different ablation time. The melting ZrO2 is helpful to promote the ablation resistance of ZrB2/20 vol.% Cu.
Keywords:Microstructure evolution  High-intensity continuous laser  Ablation behavior
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