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Corrosion resistant polymer derived ceramic composite environmental barrier coatings
Affiliation:1. University of Washington, Department of Materials Science and Engineering, Seattle, WA 98195, USA;2. Modumetal Inc., 1443 N Northlake Way, Seattle, WA 98103, USA;1. Science and Technology on Thermostructural Composite Materials Laboratory, Northwestern Polytechnical University, Xi''an, Shaanxi, 710072 China;2. State Key Laboratory of Traction Power, School of Mechanics and Engineering, Southwest Jiaotong University, Chengdu, Sichuan, 610031 China;1. Department of Materials Science and Engineering, Advanced Materials Processing and Analysis Center, University of Central Florida, Orlando, FL 32816, USA;2. School of Materials Science and Engineering, Zhengzhou University, Zhengzhou, Henan, PR China;3. Department of Mechanical Engineering, Florida State University, Tallahassee, FL, USA;1. University of Bayreuth, Ceramic Materials Engineering (CME), Ludwig-Thoma-Str. 36 B, D-95447 Bayreuth, Germany;2. Vitrum Laugaricio – Joint Glass Center of the Institute of Inorganic Chemistry, SAS, Alexander Dubček University of Trenčín, Študentská 2, 911 50 Trenčín, Slovakia;3. Technische Universität Darmstadt, Institut für Materialwissenschaft, Jovanka-Bontschits-Str. 2, D-64287 Darmstadt, Germany
Abstract:Corrosion resistant coatings are a promising solution to protect structural metals in harsh environments. Ceramic composite coatings made from polymer-derived ceramics are highly attractive due to the ease of their processing and the ability to work in various environments. This paper is focused on the performance of a TiSi2-filled SiOC ceramic composite coating system on 316 stainless steel (SS) substrates as a corrosion resistant coating. The best-performing quadruple-dip coatings were shown to be able to reduce the weight loss due to hot sulfuric acid (95+%, 104–107 °C) corrosion by 85% over a 30-day period. Coatings from the same system were also examined under 800 °C static (100 h) and cyclic (10 cycles) oxidation. Our results indicate that the coatings perform well under both conditions of prolonged high temperature oxidation and thermal cycling, suggesting the strong potential of this system as an environmental barrier coating (EBC).
Keywords:Corrosion  Oxidation  Environmental barrier coatings  Polymer derived ceramics  Composites
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