Parametric study of an efficient renewable power-to-substitute-natural-gas process including high-temperature steam electrolysis

Power-to-Substitute Natural Gas processes are investigated to offer solutions for renewable energy storing or transportation. In the present study, an original Power-to-SNG process combining high-temperature steam electrolysis and CO₂ methanation is implemented and simulated. A reference process is firstly defined, including a specific modelling approach of the electrolysis and a methanation modelling including a kinetic law. The process also integrates a unit to clean the gas from residual CO₂, H₂ and H₂O for gas network injection. Having set all the units, simulations are performed with ProsimPlus 3™ software for a reference case where the electrolyser and the methanation reactors are designed. The reference case allows to produce 67.5 Nm³/h of SNG with an electrical energy consumption of 14.4 kW h/Nm³. The produced SNG satisfies specifications required for network injection. From this reference process, two sensitivity analyses on electrolysis and methanation working points and on external parameters and constraints are considered. As a main result, we observe that the reference case maximises both process efficiency and SNG production when compared with other studied cases.