| 用空气-NO2-N2O4体系由蒽氧化生成蒽醌选择性的研究 |
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| 引用本文： | 郭睿.用空气-NO2-N2O4体系由蒽氧化生成蒽醌选择性的研究[J].西北轻工业学院学报,2004,22(4):32-34. |
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| 作者姓名： | 郭睿 |
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| 作者单位： | 郭睿（陕西科技大学化学与化工学院,陕西,咸阳,712081） |
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| 摘 要： | 以NO2-N2O4为氧化剂，在硝酸存在的条件下，对由蒽生成蒽醌的竞争反应中硝化一氧化反应的选择性进行了研究，结果表明在较高的硝酸浓度下，硝基化合物的浓度急剧减少，而蒽醌的收率增加到近乎100％。
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| 关 键 词： | 二氧化氮 蒽醌 收率 |
| 文章编号： | 1000-5811(2004)04-0032-03 |
| 修稿时间： | 2003年12月25 |
SELECTIVE STUDY OF ANTHRAQUINONE SYNTHESIS BY OXIDATION OF ANTHRACENE IN AIR-NO2-N2O4 SYSTEM |
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| GUO Rui.SELECTIVE STUDY OF ANTHRAQUINONE SYNTHESIS BY OXIDATION OF ANTHRACENE IN AIR-NO2-N2O4 SYSTEM[J].Journal of Northwest University of Light Industry,2004,22(4):32-34. |
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| Authors: | GUO Rui |
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| Abstract: | This paper studied the selective between nitration and oxidation from anthracene to anthraquinone in the presence of HNO_3 and NO_2-N_2O_4 as the oxidant. The results indicated that the concentration of nitro compounds declined sharply and the yield of anthraquinone was almost 100% in the high HNO_3 concentration. |
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| Keywords: | NO_2 anthraquinone yield |
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