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环氧树脂E-44反应增容尼龙6/废印刷电路板非金属粉复合材料的力学性能和热变形温度研究
引用本文:欧阳杰,李渊,王曦,孟勇,苏胜培. 环氧树脂E-44反应增容尼龙6/废印刷电路板非金属粉复合材料的力学性能和热变形温度研究[J]. 精细化工中间体, 2011, 41(5): 61-66
作者姓名:欧阳杰  李渊  王曦  孟勇  苏胜培
作者单位:1. 资源精细化与先进材料湖南省普通高校重点实验室,湖南长沙,410081
2. 湖南师范大学资源循环综合技术研究中心,湖南长沙,410081
3. 资源精细化与先进材料湖南省普通高校重点实验室,湖南长沙410081;湖南师范大学资源循环综合技术研究中心,湖南长沙410081
基金项目:湖南师范大学潇湘学者启动资金资助课题(化050613)
摘    要:用环氧树脂E-44作为反应性的增容剂,采用熔融共混方法制备了尼龙6(PA6)/废印刷电路板非金属粉(N-PCB)复合材料。研究了E-44用量、挤出温度以及N-PCB粉末的粒径大小对PA6/N-PCB复合材料力学性能和热变形温度的影响。对复合材料抽提残留物的红外分析实验结果表明E-44与PA6/N-PCB复合材料中PA6以及N-PCB粉末表面发生了化学键合。添加1.25份E-44的PA6/N-PCB复合材料与纯PA6相比,其拉伸强度、拉伸模量、弯曲强度和弯曲模量最大增幅分别为29%、49%、73%和72%,热变形温度提高了42.8℃,但其韧性降低。与未加增容剂相比,其拉伸强度、弯曲强度和缺口冲击强度最大增幅分别为9%、8%和43%,热变形温度提高了9.3℃。

关 键 词:环氧树脂(E-44)  尼龙6  废印刷电路板非金属粉  增容

Study on the Mechanical and Heat Distortion Temperature of Polyamide 6/Nonmetals Recycled from Waste PCB Composites Compatibilized by Epoxy Resin(E-44)
OUYANG Jie,LI Yuan,WANG Xi,MENG Yong,SU Sheng-pei. Study on the Mechanical and Heat Distortion Temperature of Polyamide 6/Nonmetals Recycled from Waste PCB Composites Compatibilized by Epoxy Resin(E-44)[J]. Fine Chemical Intermediates, 2011, 41(5): 61-66
Authors:OUYANG Jie  LI Yuan  WANG Xi  MENG Yong  SU Sheng-pei
Affiliation:OUYANG Jie1,LI Yuan1,WANG Xi1,MENG Yong2,SU Sheng-pei 1,2(1.College of Chemistry and Chemical Engineering,Key Lab of Sustainable Resources Processing and Advanced Materials,Hunan Normal University,Changsha 410081,China,2.College of Chemistry and Chemical Engineering,Recycling Integrated Technology Research Center,China)
Abstract:Polyamide 6(PA6) matrix composites,reinforced with nonmetals recycled from waste printed circuit boards(N-PCB)and compatibilized with epoxy resin(E-44),was prepared by the melt blending method.The effects of E-44 dosage,extrusion temperature and N-PCB particle sizes on the mechanical properties and heat distortion temperature of PA6/N-PCB composites were investigated.The results showed that there were chemical reactions occurred between the components of PA6/N-PCB composites,proved by both FT-IR analysis an...
Keywords:epoxy resin(E-44)  polyamide 6  nonmetals recycled from waste PCB  compatibilization  
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