| 1-对甲硫基苯基-2-甲基-2-吗啉基-1-丙酮的合成与应用 |
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| 引用本文： | 李斌栋,吕春绪,余宗学.1-对甲硫基苯基-2-甲基-2-吗啉基-1-丙酮的合成与应用[J].精细石油化工,2001(3):10-12. |
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| 作者姓名： | 李斌栋 吕春绪 余宗学 |
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| 作者单位： | 南京理工大学化工学院, |
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| 摘 要： | 以α溴代酮和甲醇钠为原料 ,甲醇为溶剂合成了中间产物 1甲氧基 1对甲硫基苯基 2 ,2二甲基环氧乙烷 ;回流状态下 ,使该中间产物与吗啉反应 ,合成了题述产物 ,纯度 99.6% ,总收率 84 .6%。并用其制UV固化涂料时 ,在空气和绝氧条件下 ,固化速度优于安息香二甲醚。
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| 关 键 词： | 光引发剂 α-溴代酮 1-对甲硫基苯基-2-甲基-2-吗啉基-1-丙酮 合成 光引发性能 |
| 修稿时间： | 2000年5月19日 |
STUDY ON THE SYNTHESIS AND APPLICATION OF 2-METHYL-1-[4-(METHYLTHIO)PHENYL]-2- MORPHOLINO-1-PROPANONE |
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| Li Bindong,Lu Chunxu,Yu Zhongxue.STUDY ON THE SYNTHESIS AND APPLICATION OF 2-METHYL-1-[4-(METHYLTHIO)PHENYL]-2- MORPHOLINO-1-PROPANONE[J].Speciality Petrochemicals,2001(3):10-12. |
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| Authors: | Li Bindong Lu Chunxu Yu Zhongxue |
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| Abstract: | The photoinitiator 2-methyl-1-［4-(methylthio)phenyl］-2-morpholino-1-propanone(Ⅰ) purity of 99.6% was synthesized form morpholino and 1-methoxy-1-［4-methylthiophenyl］-2,2-dimethyl-epoxy ethane in reflux for 16 h, which prepared by αbromoketone and sodium methylatein methanol. The yield of the product was up to 84.6%. Curing rate of the UV coation with Ⅰ is faster than that with 1,3dimethoxy benzene under air and oxygen insulation. |
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| Keywords: | photoinitiator 2methyl1[4(methylthio)phenyl]2morpholino1propanone synthesis photoinitiator |
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