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The development of hydrogen storage electrode alloys for nickel hydride batteries
Affiliation:1. Kazan State Architect and Civil Engineering University, 1 Zelenaya, 420043 Kazan, Russian Federation;2. A.E. Arbuzov Institute of Organic and Physical Chemistry, RAS, 8 Arbuzov Str., 420088 Kazan, Russian Federation;3. Kazan Department of Joint Supercomputer Center of Russian Academy of Sciences, Branch of Federal Scientific Center”Scientific Research Institute for System Analysis of the RAS, 2/31 Lobachevski Str., 4200111, Kazan, Russian Federation;4. Department of Chemistry, Moscow State University, 1-3 Lenin''s Hills, 119991 Moscow, Russian Federation
Abstract:The development of hydrogen storage electrode alloys in the 1980s resulted in the birth and growth of the rechargeable nickel hydride (Ni/MH) battery. In this paper we describe briefly a semi-empirical electrochemical/thermodynamic approach to develop/screen a hydrogen storage alloy for electrochemical application. More specifically we will discuss the ABx Ti/Zr-based alloys. Finally, the current state of the Ni/MH batteries including commercial manufacture processes, cell performance and applications is given.
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