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二次有机气溶胶中二羰基化合物的研究进展
引用本文:刘艳芬,王黎明. 二次有机气溶胶中二羰基化合物的研究进展[J]. 广东化工, 2010, 37(7): 68-69
作者姓名:刘艳芬  王黎明
作者单位:华南理工大学,化学与化工学院,广东,广州,510640;华南理工大学,化学与化工学院,广东,广州,510640
摘    要:二次有机气溶胶的形成是大气环境化学的研究热点。二羰基化合物对二次有机气溶胶形成具有重要的研究意义。由于二羰基化合物在液相中发生聚合反应,在液相中的分配大于Henry定律的预测值,影响二次有机气溶胶的形成。通过二羰基化合物乙二醛和甲基乙二醛在大气中光氧化和异相反应的研究,评述了二羰基化合物对二次有机气溶胶形成的研究发展。

关 键 词:二次有机气溶胶  二羰基化合物  乙二醛  甲基乙二醛

Research of Dicarbonyl Compounds in Secondary Organic Aerosol
Liu Yanfen,Wang Liming. Research of Dicarbonyl Compounds in Secondary Organic Aerosol[J]. Guangdong Chemical Industry, 2010, 37(7): 68-69
Authors:Liu Yanfen  Wang Liming
Affiliation:(School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China)
Abstract:The formation of secondary organic aerosol (SOA) is the research focuses in atmospheric environmental chemistry. The dicarbonyl compounds have important research significance on the formation of secondary organic aerosol. Because dicarbonyl compounds polymerization in the liquid phase, the distribution of its value in the liquid phase is greater than the predicted value of Herry's law, affecting the formation of secondary organic aerosols. In the paper, by glyoxal and methylglyoxal atmospheric photo-oxidation and heterogeneous reaction, reviewed the dicarbonyl compounds on the formation of secondary organic aerosol research and development.
Keywords:SOA  dicarbonyl compounds  glyoxal  methylglyoxal
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