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改性活性半焦脱除烟气中SO2的反应动力学
引用本文:张伟,李春虎,吴建芝. 改性活性半焦脱除烟气中SO2的反应动力学[J]. 工业催化, 2007, 15(4): 61-64
作者姓名:张伟  李春虎  吴建芝
作者单位:中国海洋大学化学化工学院,海洋化学理论与工程技术教育部重点实验室,山东 青岛 266100
摘    要:在固定床反应器中,研究用改性活性半焦来脱除烟气中SO2的动力学问题。考察半焦粒径、反应温度和空速对SO2转化率的影响,建立了本征动力学方程。反应级数为一级,表观活化能为10.058 kJ·mol-1,指前因子为69.622 2。

关 键 词:改性活性半焦  烟气脱硫  动力学   
文章编号:1008-1143(2007)04-0061-04
收稿时间:2006-10-30
修稿时间:2007-03-05

Kinetics for removal of SO2 from flue gas using modified activated semi-coke catalyst
ZHANG Wei,LI Chunhu,WU Jianzhi. Kinetics for removal of SO2 from flue gas using modified activated semi-coke catalyst[J]. Industrial Catalysis, 2007, 15(4): 61-64
Authors:ZHANG Wei  LI Chunhu  WU Jianzhi
Affiliation:The Key Laboratory of Science and Technology of Oceanic Chemistry of Ministry ;of Education,School of Chemistryand Chemical Engineering,Ocean ; University of China, Qingdao 266100,Shandong, China
Abstract:The kinetics for removal of SO2 from flue gas using modified activated semi-coke was studied in a fixed bed reactor. The influence of particulate size distribution of semi-coke, reaction temperature and space velocity on SO2 conversion was investigated and intrinsic kinetic equation established, with reaction order of 1, activation energy of 10.058 kJ·mol-1and pre-exponential factor of 69.622 2.
Keywords:modified activated semi-coke catalyst  kinetics  flue gas desulfurization
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