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环氧型丙烯酸酯橡胶的合成及特性
引用本文:黄承亚 李红. 环氧型丙烯酸酯橡胶的合成及特性[J]. 弹性体, 1994, 4(1): 1-4
作者姓名:黄承亚 李红
作者单位:华南理工大学高分子系,广州广东工学院化工系
摘    要:本文论述了含有改性单体──丙烯腈和作为硫化点单体的环氧基单体──丙烯酸缩水甘油醚的丙烯酸酯橡胶的合成及性能.实验表明环氧型ACM不能用脂肪族胺硫化.但是可用硫作促进剂、用三乙四胺迅速交联.当环氧型M的中丙烯腈含量增加时,AC的硫化胶的硬度、定伸强度和耐油性及永久变形性都有所改善.

关 键 词:环氧型 丙烯酸酯橡胶 丙烯腈 合成

THE SYNTHESES AND PROPERTIES OF EPOXY ACRYLIC RUBBER
Huang Chengya,Wuang Dizhen, Huo Qiushan. THE SYNTHESES AND PROPERTIES OF EPOXY ACRYLIC RUBBER[J]. China Elastomerics, 1994, 4(1): 1-4
Authors:Huang Chengya  Wuang Dizhen   Huo Qiushan
Affiliation:Huang Chengya;Wuang Dizhen; Huo Qiushan(Polymer Dept. of South China University of Technology)Li Hong(Chemistry Dept. of Guangdong Insitute of Technology)
Abstract:This paper is concerned with the syntheses and the properties of Acrylic Rubber(ACM) which include a modifying monomer--acrylonitrile alld an epoxy group monomer-acrylic glycidyl ether as acure-site monomer. The experimentS Show that the epoxy ACM can't be vulcanized with aliphaticamine, but with sulfur as an accelerator, it can be crosslinked rapidly with triethylene-tatramine.When acrylonitrile content increases in the epoxy ACM, the ACe vulcanizate's hardness tensilelength increase and it's oil resistance and compression set are improved.
Keywords:Epoxy ACM  Synthese  Property  Acrylic glycidyl ether  Acrylonitrile
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