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烃类晶格氧选择性氧化催化剂研究进展
引用本文:郭丛聪,李 剑,董家丽,等. 烃类晶格氧选择性氧化催化剂研究进展[J]. 当代化工, 2014, 0(4): 573-575
作者姓名:郭丛聪  李 剑  董家丽  
作者单位:辽宁石油化工大学,辽宁抚顺113001
摘    要:用晶格氧代替气相氧,是烃类选择性氧化一种新工艺,该工艺可以避免烃类的深度氧化,提高选择性,不受爆炸极限的限制,可以提高生产能力,降低成本。本文介绍了晶格氧氧化的反应机理,综述了不同烃类选择性氧化中的晶格氧催化剂的制备及应用现状,提出未来烃类选择性氧化的晶格氧催化剂的主要发展方向。

关 键 词:烃类  晶格氧  选择性氧化  催化剂

Research Progress in Lattice Oxygen Catalysts for Selective Oxidation of Hydrocarbons
GUO Cong-cong,LI Jian,DONG Jia-li,YANG Li-na. Research Progress in Lattice Oxygen Catalysts for Selective Oxidation of Hydrocarbons[J]. Contemporary Chemical Industry, 2014, 0(4): 573-575
Authors:GUO Cong-cong  LI Jian  DONG Jia-li  YANG Li-na
Affiliation:(School ofpetrochemicaltechnology, Liaoning University ofPetroleum and Technology, Liaoning Fushun 113001, China)
Abstract:Lattice oxygen replacing gas phase oxygen is a new technology of selective oxidation and partial oxidation of hydrocarbons. Through using the technology, high selectivity can be obtained because deep oxidation can be restrained. This new technology can increase productive power as well as decrease cost because it is limited by the explosion limit. In this paper, the reaction mechanism of oxidation with lattice oxygen was introduced. Present situation of lattice oxygen catalysts for selective oxidation of hydrocarbons was reviewed, and then the development tendency of the lattice oxygen catalysts was discussed.
Keywords:Hydrocarbon  Lattice oxygen  Selective oxidation  Catalyst
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