| Dimension Reduction Method in Thermodynamics of Multireaction Systems(Ⅰ)Mole Numbers,Thermodynamic Properties and Partial Molar Properties Relations |
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| 作者姓名： | 李浩然 陈志荣 韩世钧 |
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| 作者单位： | Li Haoran,Chen Zhirong and Han ShijunDepartment of Chemistry,Zhejiang University,Hangzhou 310027,China Department of Chemical Engineering,Zhejiang University,Hangzhou 310027,China |
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| 基金项目： | Supported by Zhejiang Provincial Natural Science Foundation of China. |
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| 摘 要： | When species in solution undergo multiple chemical reactions the solution may be treatedas a solution of all species actually present or as a hypothetical solution composed of unreactedindependent species.Based on the fundamental thermodynamic principle the relationships of themole numbers,the molar fractions,the thermodynamic properties and the partial molar propertiesbetween the hypothetical solution of unreacted independent species and the equilibrated solutionof actual species have been established.The hypothetical solution provides a way of reducing thedimensionality of problem and simplifying the analysis.
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