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非平衡级速率模型用于催化精馏过程的模拟计算
引用本文:吴燕翔,谭天恩,邱挺,王良恩,赵之山.非平衡级速率模型用于催化精馏过程的模拟计算[J].过程工程学报,1999,20(4):3.
作者姓名:吴燕翔  谭天恩  邱挺  王良恩  赵之山
作者单位:1. 浙江大学化工系,杭州,310013;福州大学化工系,福州,350002
2. 浙江大学化工系,杭州,310013
3. 福州大学化工系,福州,350002
基金项目:福建省自然科学基金!B97008,天津大学国家重点化学工程联合实验室资助
摘    要:采用非平衡级速率模型对醋酸甲酯水解的催化精馏中试过程进行了模拟计算,反应精馏段催化剂填料层的气相和液相传质系数用自行测定的经验关联式计算,提馏段的填料层传质系数用Onta的关联式,反应速率根据所测定的宏观反应动力学方程结合催化剂包的效率因子进行计算,得到令人满意的结果.

关 键 词:非平衡级速率模型  催化精馏  模拟计算
修稿时间:1998-10-05

APPLICATION OF THE RATE--BASED MODEL TO THE SIMULATION OFCATALYTIC DISTILLATION PROCESS
WU Yanxiang,TANTian'en,QIU Ting,WANG Liang'en,ZHAO Zhishan.APPLICATION OF THE RATE--BASED MODEL TO THE SIMULATION OFCATALYTIC DISTILLATION PROCESS[J].Chinese Journal of Process Engineering,1999,20(4):3.
Authors:WU Yanxiang  TANTian'en  QIU Ting  WANG Liang'en  ZHAO Zhishan
Abstract:The modified rate-based model for the simulation of catalytic distillation process is applied to simulate the pilot catalytic distillation process for the hydrolysis of methylacetate. The mass transfer coefficients for the catalyst packing in the reaction zone are calculated using the correlations regressed from experimental measurements and that for the stripping zone with Onta's correlations. The reaction rate is calculated on the macroscopic kineticcorrelation and measured effectiveness factor. The results are satisfactory as the compositionand temperature profiles along the column are concerned.
Keywords:Rate-based model  Catalytic distillation  Simulation
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