| KF/Al_2O_3协同TBHPAS固液相转移催化己内酰胺和酰亚胺的N烃基化反应 |
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| 引用本文： | 张传新,郭保国,司晚龄,刘振中.KF/Al_2O_3协同TBHPAS固液相转移催化己内酰胺和酰亚胺的N烃基化反应[J].精细石油化工,2001(5). |
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| 作者姓名： | 张传新 郭保国 司晚龄 刘振中 |
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| 作者单位： | 商丘师范学院化学系，商丘师范学院化学系，河南省教育学院化学系，郑州大学分析测试中心 476000，476000，郑州，450003，450052 |
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| 基金项目： | 河南省科委自然科学基金项目 ( 9740 3440 0 ) |
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| 摘 要： | 利用 KF/Al2 O3协同 TBHPAS,在固液相转移催化条件下进行己内酰胺和酰亚胺的 N烃基化 ,收率分别为 92 %～ 96%和 82 %～ 96% ,该方法简单 ,操作方便 ,是一种较为理想的 N 烃基化方法
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| 关 键 词： | 固液相转移催化 己内酰胺 酰亚胺 KF/Al2O3 TBHPAS 协同 |
N-ALKYLATION OF AZACYCLOHEPTAN2ONE AND IMIDES BY SOLIDLIQUID PHASE TRANSFER CATALYSIS UNDER TBHPAS COOPERATED WITH KFALUMINA |
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| Zhang Chuanxin ,Guo Baoguo ,Si Wanling and Liu Zhenzhong.N-ALKYLATION OF AZACYCLOHEPTAN2ONE AND IMIDES BY SOLIDLIQUID PHASE TRANSFER CATALYSIS UNDER TBHPAS COOPERATED WITH KFALUMINA[J].Speciality Petrochemicals,2001(5). |
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| Authors: | Zhang Chuanxin Guo Baoguo Si Wanling and Liu Zhenzhong |
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| Affiliation: | Zhang Chuanxin 1,Guo Baoguo 1,Si Wanling 2 and Liu Zhenzhong 3 |
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| Abstract: | NAlkylation of azacycloheptan2one (caprolactam) and imides by solidliquid phase transfer catalysis under TBHPAS cooperated with KF/Al 2O 3 was carried out in good yield. This method has the advantages of mild condition, simplicity and convenient work up. |
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| Keywords: | solidliquid PTC imide caprolactam KF/Al 2O 3 TBHPAS cooperation |
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