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Tuning the interlaminar shear strength and thermo-mechanical properties of glass fiber composites by incorporation of (3-mercaptopropyl) trimethoxysilane-functionalized carbon black
Authors:Fahd Jamshaid  Adnan Ahmad  Muhammad Adrees  Sadia Sagar Iqbal  Hira Zaheer  Tahir Jamil  Javaid Ahmad  Tousif Hussain
Affiliation:1.Department of Polymer Engineering and Technology,University of the Punjab,Lahore,Pakistan;2.Department of Chemical Engineering,COMSATS Institute of Information Technology,Lahore,Pakistan;3.The Center for Advanced Studies in Physics,Government College University,Lahore,Pakistan
Abstract:The incorporation of functionalized nanoscale fillers into traditional glass fiber/unsaturated polyester (GF/UPE) composites provides a more robust mechanical attributes. The current study demonstrates the potential of 3-mercaptopropyl trimethoxysilane (MPTS)-functionalized carbon black (f-CB) for enhancing the thermo-mechanical properties of GF composites. The composites infused with 1, 3 and 5 wt% of pristine and MPTS-functionalized CB were fabricated by hand lay-up and hot press processing. Tensile testing, interlaminar shear strength (ILSS) testing and dynamic mechanical analysis were used to evaluate the performance of nanocomposites. Fourier transform infrared spectroscopy validated the MPTS functionalization of CB. Pristine CB-loaded nanocomposites exhibited marginal improvement in ultimate tensile strength (UTS), ILSS and thermo-mechanical properties. However, with the addition of f-CB, the improvement in all the studied properties was more substantial. The inclusion of 5 wt% f-CB increased the elastic modulus and UTS by 16 and 22%, respectively, whereas the ILSS was enhanced by 36%, in comparison to the neat GF composite. The scanning electron microscope analysis of fractured ILSS samples revealed better fiber-matrix adhesion and compatibility in f-CB-loaded nanocomposites. At the same filler weight percentage, the storage modulus at 25 °C was ~ 19% higher than that of neat composite. The f-CB inclusion resulted in increment of T g by ~ 13 °C over the T g of neat GF/UPE composite (~ 109 °C). These improvements were due to the chemical connection of f-CB to the UPE matrix and GF surface. With such improvements in thermal and mechanical properties, these nanocomposites can replace the conventional GF composites with prominent improvements in performance.
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