Evolution of aggregation structure of polyacrylonitrile fibers in the cyclization reaction

The aggregation structure of polyacrylonitrile precursor evolves gradually with progress of cyclization. In this work, the variety of cyclization degrees were determined by Fourier transform infrared spectroscopy and the evolution of aggregation structure of PAN fibers were characterized by wide‐angle X‐ray diffraction. Experimental results showed that the cyclization occurred first in the amorphous parts when the heating temperature was below 200°C. After heated at 200°C for 30 min, molecular chains in the pseudo‐crystalline regions started to pack into crystalline regions due to the increasing stress which was produced by cyclization occurred in the amorphous phase, and the crystallinity and crystallite size increased slowly. When the temperature reached to 220°C, pseudo‐crystalline regions rearranged obviously under stress, while molecular chains in the crystalline region started to participate in cyclization, and the original crystalline structures were destructed. The two competitive processes induced that the crystallinity and crystallite size grew to the maximum values at 30 min. When the temperature up to 240°C, the cyclization occurred in the crystalline region became more intensely, while the crystallinity and crystallite size decreased out of synchronize. A scheme of evolution of aggregation structure in cyclization was modified based on the above results. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012