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萃取法分离钪与铁的研究
引用本文:于永波.萃取法分离钪与铁的研究[J].山西冶金,2014(2):19-20.
作者姓名:于永波
作者单位:山西机电职业技术学院材料工程系,山西长治046000
摘    要:赤泥是铝工业生产过程中的废弃物,其中含有有价值的金属钪,通过盐酸浸出、有机溶剂萃取可实现钪的富集分离。当选用w(P204)为1%和w(TBP)为1%的萃取剂、1∶1的V(O)∶V(A)(O为有机相,A为水相)时,在3 mol/L的酸度下进行10 min振荡萃取后,钪的提取率可达到90%以上,铁的提取率只有3.6%,钪与铁的分离系数为312,为后续钪的进一步提取提供了有力的条件。

关 键 词:赤泥  萃取    

Investigation on Extraction and Separation of Scandium and Iron
Yu Yongbo.Investigation on Extraction and Separation of Scandium and Iron[J].Shanxi Metallurgy,2014(2):19-20.
Authors:Yu Yongbo
Affiliation:Yu Yongbo ( Department of Materials Engineering, Shanxi Mechanical and Electrical Professional Technology Institute, Changzhi Shanxi 046000 )
Abstract:Red mud is polluted waste in the course of production of aluminium,containing valuable metallic Scandium. By hydrochloric acid leaching, solvent extraction can realize the enrichment and separation of scandium. When the mass fraction of P204 and TBP is 1%, the O/A ratio is 1:1,the acidity is 3mol/L, the oscillation time is 10min,the extracting rate of Scandium is more than 90% ,and the extracting rate of Fe is 3.6%.The separation coefficient of Sc and Fe is 312,providing a good conditions for subsequent scandium extraction.
Keywords:red mud  extracting  scandium  iron
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