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Role of La2O3 in Pd-Supported Catalysts for Methanol Decomposition
Authors:Cheng Yang  Jie Ren  Yuhan Sun
Affiliation:(1) State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Science, P.O. Box 165, Taiyuan, 030001, People's Republic of China
Abstract:Systems of Pd supported on various La2O3-modified gamma-Al2O3 and CeO2–Al2O3 catalysts were tested for catalytic methanol decomposition and characterized by means of XRD, BET, TPR, H2-chemisorption and CO–FTIR. The addition of lanthanum significantly improved the selectivity of CO and H2 for all the catalysts but showed a different influence on the catalytic activity in two systems. Methanol conversion decreased on La2O3-modified Pd/gamma-Al2O3 catalysts, in line with the reduction of Pd dispersion, while the addition of La2O3 improved the dispersion of Pd and reinforced Pd–CeO2 interaction for La2O3-modified Pd/CeO2–Al2O3 catalysts, which resulted in a high production rate of CO and H2. Thus, a synergistic effect between CeO2 and La2O3 was observed on gamma-Al2O3-supported Pd catalyst for methanol decomposition.
Keywords:methanol decomposition  La2O3  CeO2  Pd/gamma-Al2O3" target="_blank">gif" alt="gamma" align="MIDDLE" BORDER="0">-Al2O3  synergistic effect
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