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低温柔韧型高硬度水性聚氨酯分散体的合成与性能研究
引用本文:朱宁香,叶代勇,陈焕钦.低温柔韧型高硬度水性聚氨酯分散体的合成与性能研究[J].上海涂料,2007,45(3):29-33.
作者姓名:朱宁香  叶代勇  陈焕钦
作者单位:华南理工大学,化工与能源学院,广州,510640;广东嘉宝莉化工有限公司,江门,529085;华南理工大学,化工与能源学院,广州,510640
基金项目:粤港关键领域重点突破项目
摘    要:制备了具有核壳结构的水性聚氨酯-丙烯酸酯(WPUA)复合分散体。研究了NCO/OH摩尔比、醇扩链剂、亲水性扩链剂、E-20、MMA等对分散体及涂膜性能的影响,从而确定了最佳合成配方,获得了低温成膜性好、贮存稳定性好、高硬度、耐水性佳的水性聚氨酯分散体及其涂料。

关 键 词:水性聚氨酯  环氧树脂  甲基丙烯酸甲酯
文章编号:1009-1696(2007)03-0029-05
收稿时间:2007-01-29
修稿时间:2007年1月29日

Synthesis and Performance Research of Water-borne Polyurethane Dispersion with High Hardness and Excellent Flexibility at Low Temperature
ZHU Ning-xiang,YE Dai-yong,CHEN Huan-qin.Synthesis and Performance Research of Water-borne Polyurethane Dispersion with High Hardness and Excellent Flexibility at Low Temperature[J].Shanghai Coatings,2007,45(3):29-33.
Authors:ZHU Ning-xiang  YE Dai-yong  CHEN Huan-qin
Affiliation:ZHU Ning-xiang YE Dai-yong CHEN Huan-qin
Abstract:Water-borne polyurethane/acrylate dispersion(WPUA)with core/shell structure was prepared.The influences of ratio of NCO/OH,and chain extender etc.upon the performance of the dispersion and its film were discussed.An excellent polyurethane dispersion with good flexibility,stability,high hardness,good water-resistance was obtained.
Keywords:water-borne polyurethane  epoxy resin  methyl-methacylate(MMA)
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