| 乙撑双膦酸四甲酯的合成研究 |
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| 引用本文： | 纪孝熹,刁建高,王彦林.乙撑双膦酸四甲酯的合成研究[J].塑料助剂,2010(6):27-29. |
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| 作者姓名： | 纪孝熹 刁建高 王彦林 |
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| 作者单位： | 苏州科技学院化学与生物工程学院,苏州215009 |
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| 摘 要： | 以1,2-二溴乙烷、亚磷酸三甲酯为原料,合成阻燃剂乙撑双膦酸四甲酯,其最适宜的合成条件为二溴乙烷、亚磷酸三甲酯的摩尔比为1:3.5,在175℃下反应时8h,产品得率为7.15%,并用红外、核磁、元素分析等对产品进行表征。
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| 关 键 词： | 阻燃剂 1 2-二溴乙烷 亚磷酸三甲酯 乙撑双膦酸四甲酯 合成 |
Study on Synthesis of Tetraethyl Ethylenediphosphonate |
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| Ji Xiao-xi,Diao Jian-gao,Wang Yan-lin.Study on Synthesis of Tetraethyl Ethylenediphosphonate[J].Plastic Additives,2010(6):27-29. |
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| Authors: | Ji Xiao-xi Diao Jian-gao Wang Yan-lin |
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| Affiliation: | Ji Xiao-xi Diao Jian-gao Wang Yan-lin(Chemistry and Biological Engineering College,University of Science and Technology of Suzhou,Suzhou,215009) |
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| Abstract: | An flame retardant tetraethyl ethylenediphosphonate was synthesized through 1,2-ethylene dibromide,trimethyl phosphite,and the best synthesis conditions were optimized as follows：the molar ratio of the ethylene dibromide and trimethyl phosphite is 1：3.5 while the reaction is carried out under 176 ℃ for 8 h,and the yield is 7.15%.The obtained product was characterized by IR,NMR spectra,and element analysis. |
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| Keywords: | flame retardant 1 2-ethylene dibromide trimethyl phosphite tetraethyl ethylenediphosphonate synthesis |
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