Synthesis and characterization of polyamides and poly(amide-imide)s based on ether-sulfone-diamines |
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Authors: | Sheng-Huei Hsiao Chin-Ping Yang Chin-Tang Li |
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Affiliation: | (1) Department of Chemical Engineering, Tatung Institute of Technology, 40 Chungshan North Rd., Sec.3, Taipei, 10451, Taiwan, ROC |
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Abstract: | A series of polyamides and poly(amide-imide)s were prepared by the direct polycondensation of 4,4′-sulfonylbis(1,4-phenyleneoxy)]dianiline
or 4,4′-sulfonylbis(2,6-dimethyl-1,4-phenyleneoxy)]dianiline with aromatic dicarboxylic acids and phthalimide unit-bearing
dicarboxylic acids in a N-methyl-2-pyrrolidone (NMP) solution containing dissolved calcium chloride using triphenyl phosphite and pyridine as condensing
agents. The inherent viscosities of the resulting polymers were above 0.45 dL/g and up to 1.70 dL/g. Except for the polyamides
derived from terephthalic acid and 4,4′-biphenyldicarboxylic acid, all the other polyamides and all poly(amide-imide)s were
readily soluble in polar organic solvents such as NMP, N, N-dimethylacetamide (DMAc), N,N-dimethylformamide (DMF), dimethyl sulfoxide (DMSO), and m-cresol, and afforded transparent and tough films by solution-casting. Most of the polymers showed distinct glass transition
on their differential scanning calorimetry (DSC) traces and their glass transition temperatures (Tg) stayed between 140–264 °C. The methyl-substituted polymers showed higher Tgs than the corresponding unsubstituted counterparts. The results of the thermogravimetry analysis (TGA) revealed that all
the methyl-substituted polymers showed lower initial decomposition temperatures than the unsubstituted ones. |
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Keywords: | Polyamides Poly(amide-imide)s Ether-sulfone-diamines Methyl substituent Solubility Tgs |
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