| A CYCLING PERFORMANCE MODEL FOR THE ZINC/FERRICYANIDE BATTERY |
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| 作者姓名： | 杨敏之 吴扦 J. ROBERT SELMAN |
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| 作者单位： | Shanghai Jiao Tong University Shanghai，Illinosi Institute of technology，Chicago，U.S.A.，Illinois Institute of Technology，Chicago，U.S.A. |
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| 摘 要： | A model is presented for the charge and discharge cyele of a zine-redox battery, based on the available steady-state cell performance model. The cycling model makes use of a quasi-steady-state assumption and includes the effects of crystallization and membrane water transport on the volume of electrolyte during a cycle, as well as variable IR-drop due to conductivity changes. Performance predictions of this model are compared with selected experimental charge/discharge data. Small adjustments to the equilibrium cell potential and cell resistance are made to make the model suitable for design optimization.
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| 修稿时间： | |
A CYCLING PERFORMANCE MODEL FOR THE ZINC/FERRICYANIDE BATTERY |
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| YANG Minzhi,HAN Wu,J. ROBERT SELMAN.A CYCLING PERFORMANCE MODEL FOR THE ZINC/FERRICYANIDE BATTERY[J].Chinese Journal of Chemical Engineering,1989,4(1):93-114. |
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| Authors: | YANG Minzhi HAN Wu J ROBERT SELMAN |
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| Affiliation: | Shanghai Jiao Tong University, Shanghai
Illinosi Institute of technology, Chicago, U.S.A. |
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| Abstract: | A model is presented for the charge and discharge cyele of a zine-redox battery, based on the available steady-state cell performance model. The cycling model makes use of a quasi-steady-state assumption and includes the effects of crystallization and membrane water transport on the volume of electrolyte during a cycle, as well as variable IR-drop due to conductivity changes. Performance predictions of this model are compared with selected experimental charge/discharge data. Small adjustments to the equilibrium cell potential and cell resistance are made to make the model suitable for design optimization. |
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