Temperature effects on ZnO electrodeposition |
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Authors: | A. Goux J. Chivot |
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Affiliation: | a Laboratoire d’Electrochimie et Chimie Analytique UMR-CNRS 7575, Ecole Nationale Supérieure de Chimie de Paris, 11 rue P. et M. Curie, 75231 Paris cedex 05, France b DPC/SCCME, Centre d’Etudes Nucléaires de Saclay, 91131 Gif-sur-Yvette cedex, France |
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Abstract: | A thermochemical study of the temperature effects on the Zn-Cl-H2O system by means of potential-pH, solubility and species repartition diagrams is presented with the view to better understand the effect of temperature on the deposition mechanism and composition of zinc oxide thin films. These calculations have been completed by film preparation at different temperatures between room temperature and 90 °C. Below 34 °C, we observe the absence of continuous film growth and surface passivation. The oxide nucleation and film growth start above 34 °C, whereas the optimum film transparency and crystallinity is obtained from 40 °C. Above, the main effect of the temperature is to raise the film texturation with the c-axis perpendicular to the substrate surface. |
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Keywords: | Electrodeposition Zinc oxide Thermodynamical study Temperature |
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