Pressure effect on optical properties and structure stability of LaPO<sub>4</sub>:Eu<sup>3+</sup> hollow spheres |
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Authors: | ZHAO Zhi ZUO Jian DING Zejun |
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Affiliation: | (Hefei National Laboratory for Physical Sciences at the Microscale,University o f Science and Technology of China,Hefei 230026,China) |
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Abstract: | Uniform monoclinic monazite structure LaPO4:Eu3+ hollow spheres were s ynthesized via an attractive hydrothermal method owing to the higher yield and s implicity.Photoluminescence and Raman spectra of the sample were investigated u nder high pressure up to 26 GPa using diamond anvil cells.At ambient pressure,the sample exhibited same luminescent properties with that of bulk monazite LaPO 4:Eu3+.With the increase of pressure,the emission intensity of Eu3+ decreased and the half-widths of transition lines increased,while emission peaks showed a red shift toward longer wavelengths due to increase in crystal-field strength.No phase transformation appeared before amorphization for monoclinic LaPO4:Eu3+ hollow spheres,which was confirmed based on the analysis of high pressure Raman spectra.The large surface energy of hollow spheres was proposed to prevent the occurrence of phase transformation. |
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Keywords: | LaPO4:Eu3+ hollow spheres hydrothermal high pressure Raman photolu minescence rare earths |
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